After losing the first leg 3-2 a week prior, Manchester City faced a challenging task to reverse the outcome at the Santiago Bernabeu.
However, a remarkable hat trick from French striker Kylian Mbappe sealed their fate, resulting in a 3-1 defeat against Carlo Ancelotti's squad.
In another match that evening, Dutch champions PSV Eindhoven triumphed over Juventus to secure a place in the last 16. Additionally, PSG achieved victory against fellow French team Brest, advancing to the next stage of Europe's premier competition.
Champions League play-off matches were also held on Tuesday.
Knockout phase play-offs ✅#UCL pic.twitter.com/Z3VuK7LjWm
— UEFA Champions League (@ChampionsLeague) February 20, 2025
Teams in UCL Last 16
Here is a list of teams that have qualified for the UEFA Champions League last 16 after the knockout phase playoffs were concluded on Wednesday:
Qualified automatically
Round of 16 set ✅#UCL pic.twitter.com/KwvwwRtxUa
— UEFA Champions League (@ChampionsLeague) February 19, 2025
Liverpool, Barcelona, Arsenal, Inter Milan, Atletico Madrid, Bayer Leverkusen, Lille, Aston Villa
Qualified via knockout phase play-offs
Borussia Dortmund, Real Madrid, Bayern Munich, PSV Eindhoven, Paris Saint-Germain, Benfica, Feyenoord, Club Brugge
Note: Last 16 draw takes place on Friday (1100 GMT)